Silicon α-Effect: A Systematic Experimental and Computational Study of the Hydrolysis of Cα- and Cγ-Functionalized Alkoxytriorganylsilanes of the Formula Type ROSiMe2(CH2)nX (R = Me, Et; n = 1, 3; X = Functional Group)

A. Berkefeld; C. Fonseca Guerra; R. Bertermann; D. Troegel; J. Daiss; J. Stohrer; F.M. Bickelhaupt; R. Tacke

doi:10.1021/om500073m

Silicon α-Effect: A Systematic Experimental and Computational Study of the Hydrolysis of Cα- and Cγ-Functionalized Alkoxytriorganylsilanes of the Formula Type ROSiMe2(CH2)nX (R = Me, Et; n = 1, 3; X = Functional Group)

A. Berkefeld, C. Fonseca Guerra, R. Bertermann, D. Troegel, J. Daiss, J. Stohrer, F.M. Bickelhaupt, R. Tacke

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

To understand the silicon α-effect in terms of an enhanced reactivity of the Si-OC bond of α-silanes of the formula type ROSiMe

Original language	English
Pages (from-to)	2721-2737
Journal	Organometallics
Volume	33
DOIs	https://doi.org/10.1021/om500073m
Publication status	Published - 2014

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Berkefeld, A., Fonseca Guerra, C., Bertermann, R., Troegel, D., Daiss, J., Stohrer, J., Bickelhaupt, F. M., & Tacke, R. (2014). Silicon α-Effect: A Systematic Experimental and Computational Study of the Hydrolysis of Cα- and Cγ-Functionalized Alkoxytriorganylsilanes of the Formula Type ROSiMe2(CH2)nX (R = Me, Et; n = 1, 3; X = Functional Group). Organometallics, 33, 2721-2737. https://doi.org/10.1021/om500073m

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title = "Silicon α-Effect: A Systematic Experimental and Computational Study of the Hydrolysis of Cα- and Cγ-Functionalized Alkoxytriorganylsilanes of the Formula Type ROSiMe2(CH2)nX (R = Me, Et; n = 1, 3; X = Functional Group)",

abstract = "To understand the silicon α-effect in terms of an enhanced reactivity of the Si-OC bond of α-silanes of the formula type ROSiMe",

author = "A. Berkefeld and {Fonseca Guerra}, C. and R. Bertermann and D. Troegel and J. Daiss and J. Stohrer and F.M. Bickelhaupt and R. Tacke",

year = "2014",

doi = "10.1021/om500073m",

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volume = "33",

pages = "2721--2737",

journal = "Organometallics",

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Berkefeld, A, Fonseca Guerra, C, Bertermann, R, Troegel, D, Daiss, J, Stohrer, J, Bickelhaupt, FM & Tacke, R 2014, 'Silicon α-Effect: A Systematic Experimental and Computational Study of the Hydrolysis of Cα- and Cγ-Functionalized Alkoxytriorganylsilanes of the Formula Type ROSiMe2(CH2)nX (R = Me, Et; n = 1, 3; X = Functional Group)', Organometallics, vol. 33, pp. 2721-2737. https://doi.org/10.1021/om500073m

Silicon α-Effect: A Systematic Experimental and Computational Study of the Hydrolysis of Cα- and Cγ-Functionalized Alkoxytriorganylsilanes of the Formula Type ROSiMe2(CH2)nX (R = Me, Et; n = 1, 3; X = Functional Group). / Berkefeld, A.; Fonseca Guerra, C.; Bertermann, R. et al.
In: Organometallics, Vol. 33, 2014, p. 2721-2737.

Research output: Contribution to Journal › Article › Academic › peer-review

TY - JOUR

T1 - Silicon α-Effect: A Systematic Experimental and Computational Study of the Hydrolysis of Cα- and Cγ-Functionalized Alkoxytriorganylsilanes of the Formula Type ROSiMe2(CH2)nX (R = Me, Et; n = 1, 3; X = Functional Group)

AU - Berkefeld, A.

AU - Fonseca Guerra, C.

AU - Bertermann, R.

AU - Troegel, D.

AU - Daiss, J.

AU - Stohrer, J.

AU - Bickelhaupt, F.M.

AU - Tacke, R.

PY - 2014

Y1 - 2014

N2 - To understand the silicon α-effect in terms of an enhanced reactivity of the Si-OC bond of α-silanes of the formula type ROSiMe

AB - To understand the silicon α-effect in terms of an enhanced reactivity of the Si-OC bond of α-silanes of the formula type ROSiMe

U2 - 10.1021/om500073m

DO - 10.1021/om500073m

M3 - Article

SN - 1520-6041

VL - 33

SP - 2721

EP - 2737

JO - Organometallics

JF - Organometallics

ER -