Silylene-Induced Reduction of [Mn2(CO)10]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)4Mn=Mn(CO)4]2– Ligand

Johannes A. Baus; Jordi Poater; F. Matthias Bickelhaupt; Reinhold Tacke

doi:10.1002/ejic.201600913

Silylene-Induced Reduction of [Mn₂(CO)₁₀]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)₄Mn=Mn(CO)₄]^2– Ligand

Johannes A. Baus, Jordi Poater, F. Matthias Bickelhaupt^*, Reinhold Tacke

^*Corresponding author for this work

Research output: Contribution to Journal › Article › Academic › peer-review

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Abstract

Treatment of the donor-stabilized silylene [iPrNC(NiPr₂)NiPr]₂Si (1) with [Mn₂(CO)₁₀] leads to the five-coordinate silicon(IV) complex 6, accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC)₄Mn=Mn(CO)₄]^2– moiety that is coordinated to the silicon(IV) species {[iPrNC(NiPr₂)NiPr]₂Si}²⁺.

Original language	English
Pages (from-to)	186-191
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Volume	2017
Issue number	1
Early online date	23 Dec 2016
DOIs	https://doi.org/10.1002/ejic.201600913
Publication status	Published - 3 Jan 2017

Funding

R. T. thanks the Deutsche Forschungsgemeinschaft (grant TA 75/16-1), F. M. B. thanks the Netherlands Organization for Scientific Research (NWO-CW, NWO-ALW, NWO-EW), and J. P. thanks the MINECO (CTQ2016-77558-R) for financial support.

Funders	Funder number
NWO-ALW
NWO-CW
NWO-EW
Deutsche Forschungsgemeinschaft	TA 75/16-1
Nederlandse Organisatie voor Wetenschappelijk Onderzoek
Ministerio de Economía y Competitividad	CTQ2016-77558-R

Keywords

Density functional calculations
Guanidinato ligands
Manganese
Silicon
Silylenes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/ejic.201600913

Baus - Silylene‐Induced Reduction of Mn2 CO 10 Formation of a Five‐Coordinate Silicon IVFinal published version, 1.38 MBLicence: Article 25fa Dutch Copyright Act

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title = "Silylene-Induced Reduction of [Mn2(CO)10]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)4Mn=Mn(CO)4]2– Ligand",

abstract = "Treatment of the donor-stabilized silylene [iPrNC(NiPr2)NiPr]2Si (1) with [Mn2(CO)10] leads to the five-coordinate silicon(IV) complex 6, accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC)4Mn=Mn(CO)4]2– moiety that is coordinated to the silicon(IV) species {[iPrNC(NiPr2)NiPr]2Si}2+.",

keywords = "Density functional calculations, Guanidinato ligands, Manganese, Silicon, Silylenes",

author = "Baus, {Johannes A.} and Jordi Poater and Bickelhaupt, {F. Matthias} and Reinhold Tacke",

year = "2017",

month = jan,

day = "3",

doi = "10.1002/ejic.201600913",

language = "English",

volume = "2017",

pages = "186--191",

journal = "European Journal of Inorganic Chemistry",

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publisher = "Wiley-VCH Verlag",

number = "1",

}

Silylene-Induced Reduction of [Mn₂(CO)₁₀]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)₄Mn=Mn(CO)₄]^2– Ligand. / Baus, Johannes A.; Poater, Jordi; Bickelhaupt, F. Matthias et al.
In: European Journal of Inorganic Chemistry, Vol. 2017, No. 1, 03.01.2017, p. 186-191.

Research output: Contribution to Journal › Article › Academic › peer-review

TY - JOUR

T1 - Silylene-Induced Reduction of [Mn2(CO)10]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)4Mn=Mn(CO)4]2– Ligand

AU - Baus, Johannes A.

AU - Poater, Jordi

AU - Bickelhaupt, F. Matthias

AU - Tacke, Reinhold

PY - 2017/1/3

Y1 - 2017/1/3

N2 - Treatment of the donor-stabilized silylene [iPrNC(NiPr2)NiPr]2Si (1) with [Mn2(CO)10] leads to the five-coordinate silicon(IV) complex 6, accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC)4Mn=Mn(CO)4]2– moiety that is coordinated to the silicon(IV) species {[iPrNC(NiPr2)NiPr]2Si}2+.

AB - Treatment of the donor-stabilized silylene [iPrNC(NiPr2)NiPr]2Si (1) with [Mn2(CO)10] leads to the five-coordinate silicon(IV) complex 6, accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC)4Mn=Mn(CO)4]2– moiety that is coordinated to the silicon(IV) species {[iPrNC(NiPr2)NiPr]2Si}2+.

KW - Density functional calculations

KW - Guanidinato ligands

KW - Manganese

KW - Silicon

KW - Silylenes

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U2 - 10.1002/ejic.201600913

DO - 10.1002/ejic.201600913

M3 - Article

AN - SCOPUS:85007358711

SN - 1434-1948

VL - 2017

SP - 186

EP - 191

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 1

ER -

Silylene-Induced Reduction of [Mn₂(CO)₁₀]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)₄Mn=Mn(CO)₄]^2– Ligand

Abstract

Funding

Keywords

UN SDGs

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CCDC 1482511: Experimental Crystal Structure Determination

Cite this

Silylene-Induced Reduction of [Mn2(CO)10]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)4Mn=Mn(CO)4]2– Ligand

Abstract

Funding

Keywords

UN SDGs

Access to Document

Persistent URL (handle)

Other files and links

Fingerprint

Datasets

CCDC 1482511: Experimental Crystal Structure Determination

Cite this

Silylene-Induced Reduction of [Mn₂(CO)₁₀]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)₄Mn=Mn(CO)₄]^2– Ligand