Single short-column liquid chromatography with atmospheric pressure chemical ionization - (tandem) mass spectrometric detection for trace environmental analysis.

A.C. Hogenboom; J.J. Vreuls; J.A. Rontree; B.L.M. van Baar; W.M.A. Niessen; U.A.T. Brinkman; J. Slobodník

doi:10.1007/BF02290284

Single short-column liquid chromatography with atmospheric pressure chemical ionization - (tandem) mass spectrometric detection for trace environmental analysis.

A.C. Hogenboom, J.J. Vreuls, J.A. Rontree, B.L.M. van Baar, W.M.A. Niessen, U.A.T. Brinkman, J. Slobodník

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Single short, i.e. ca 2-cm long, high-pressure-packed columns coupled with mass spectrometric (MS) or tandem MS detection enable rapid trace-level determination and identification of environmental pollutants in water samples. In this study an atmospheric pressure chemical ionization (APCI) interface has been used and the overall set-up was tested with a mixture of seventeen pesticides, including organophosphates, carbamates, phenylureas and triazines. For the majority of the test analytes, the most prominent peaks in the positive-ion APCI-MS spectra resulted from protonated molecules. For fifteen out of the seventeen pesticides short-column liquid chromatography (LC)-APCI-MS of water samples as small as 15 mL resulted in detection limits between 0.03 and 5 μg L

Original language	English
Pages (from-to)	506
Journal	Chromatographia
Volume	42
Issue number	9/10
DOIs	https://doi.org/10.1007/BF02290284
Publication status	Published - 1996

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@article{e2c1bef333994c289644b906ac33cdf4,

title = "Single short-column liquid chromatography with atmospheric pressure chemical ionization - (tandem) mass spectrometric detection for trace environmental analysis.",

abstract = "Single short, i.e. ca 2-cm long, high-pressure-packed columns coupled with mass spectrometric (MS) or tandem MS detection enable rapid trace-level determination and identification of environmental pollutants in water samples. In this study an atmospheric pressure chemical ionization (APCI) interface has been used and the overall set-up was tested with a mixture of seventeen pesticides, including organophosphates, carbamates, phenylureas and triazines. For the majority of the test analytes, the most prominent peaks in the positive-ion APCI-MS spectra resulted from protonated molecules. For fifteen out of the seventeen pesticides short-column liquid chromatography (LC)-APCI-MS of water samples as small as 15 mL resulted in detection limits between 0.03 and 5 μg L",

author = "A.C. Hogenboom and J.J. Vreuls and J.A. Rontree and {van Baar}, B.L.M. and W.M.A. Niessen and U.A.T. Brinkman and J. Slobodn{\'i}k",

year = "1996",

doi = "10.1007/BF02290284",

language = "English",

volume = "42",

pages = "506",

journal = "Chromatographia",

issn = "0009-5893",

publisher = "Springer",

number = "9/10",

}

TY - JOUR

T1 - Single short-column liquid chromatography with atmospheric pressure chemical ionization - (tandem) mass spectrometric detection for trace environmental analysis.

AU - Hogenboom, A.C.

AU - Vreuls, J.J.

AU - Rontree, J.A.

AU - van Baar, B.L.M.

AU - Niessen, W.M.A.

AU - Brinkman, U.A.T.

AU - Slobodník, J.

PY - 1996

Y1 - 1996

N2 - Single short, i.e. ca 2-cm long, high-pressure-packed columns coupled with mass spectrometric (MS) or tandem MS detection enable rapid trace-level determination and identification of environmental pollutants in water samples. In this study an atmospheric pressure chemical ionization (APCI) interface has been used and the overall set-up was tested with a mixture of seventeen pesticides, including organophosphates, carbamates, phenylureas and triazines. For the majority of the test analytes, the most prominent peaks in the positive-ion APCI-MS spectra resulted from protonated molecules. For fifteen out of the seventeen pesticides short-column liquid chromatography (LC)-APCI-MS of water samples as small as 15 mL resulted in detection limits between 0.03 and 5 μg L

AB - Single short, i.e. ca 2-cm long, high-pressure-packed columns coupled with mass spectrometric (MS) or tandem MS detection enable rapid trace-level determination and identification of environmental pollutants in water samples. In this study an atmospheric pressure chemical ionization (APCI) interface has been used and the overall set-up was tested with a mixture of seventeen pesticides, including organophosphates, carbamates, phenylureas and triazines. For the majority of the test analytes, the most prominent peaks in the positive-ion APCI-MS spectra resulted from protonated molecules. For fifteen out of the seventeen pesticides short-column liquid chromatography (LC)-APCI-MS of water samples as small as 15 mL resulted in detection limits between 0.03 and 5 μg L

U2 - 10.1007/BF02290284

DO - 10.1007/BF02290284

M3 - Article

SN - 0009-5893

VL - 42

SP - 506

JO - Chromatographia

JF - Chromatographia

IS - 9/10

ER -

Single short-column liquid chromatography with atmospheric pressure chemical ionization - (tandem) mass spectrometric detection for trace environmental analysis.

Abstract

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