Strained Stable 2-Aza-1-Phosphabicyclo[/n/.1.0]alkane and -alkene Fe(CO4) Complexes with Dynamic Phosphinidene Behavior

M.L.G. Borst; N. van der Riet; R.H. Lemmens; F.J.J. De Kanter; M. Schakel; A.W. Ehlers; A.M. Mills; M. Lutz; A.L. Spek; K. Lammertsma

doi:10.1002/chem.200401249

Strained Stable 2-Aza-1-Phosphabicyclo[/n/.1.0]alkane and -alkene Fe(CO4) Complexes with Dynamic Phosphinidene Behavior

M.L.G. Borst, N. van der Riet, R.H. Lemmens, F.J.J. De Kanter, M. Schakel, A.W. Ehlers, A.M. Mills, M. Lutz, A.L. Spek, K. Lammertsma

Organic Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

The synthesis of highly strained bicyclic phosphirane and phosphirene iron-tetracarbonyl complexes, that is, complexes with 2-aza-l-phosphabicyclo[n. 1.0]alkanes and -alkenes (n = 3-5), is explored by using intramolecular cycloaddition of an in situ generated electrophilic phosphinidene complex, [R(iPr)NP=Fe(CO)

Original language	English
Pages (from-to)	3631-3642
Journal	Chemistry: A European Journal
Volume	11
DOIs	https://doi.org/10.1002/chem.200401249
Publication status	Published - 2005

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10.1002/chem.200401249

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CCDC 256108: Experimental Crystal Structure Determination
Borst, M. L. G. (Contributor), Van Der Riet, N. (Contributor), Lemmens, R. H. (Contributor), De Kanter, F. J. J. (Contributor), Schakel, M. (Contributor), Ehlers, A. W. (Contributor), Mills, A. M. (Contributor), Lutz, M. (Contributor), Spek, A. L. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 1 Jan 2005
DOI: 10.5517/cc8lhkw, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8lhkw&sid=DataCite
Dataset / Software: Dataset
CCDC 256107: Experimental Crystal Structure Determination
Borst, M. L. G. (Contributor), Van Der Riet, N. (Contributor), Lemmens, R. H. (Contributor), De Kanter, F. J. J. (Contributor), Schakel, M. (Contributor), Ehlers, A. W. (Contributor), Mills, A. M. (Contributor), Lutz, M. (Contributor), Spek, A. L. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 1 Jan 2005
DOI: 10.5517/cc8lhjv, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8lhjv&sid=DataCite
Dataset / Software: Dataset
CCDC 256109: Experimental Crystal Structure Determination
Borst, M. L. G. (Contributor), Van Der Riet, N. (Contributor), Lemmens, R. H. (Contributor), De Kanter, F. J. J. (Contributor), Schakel, M. (Contributor), Ehlers, A. W. (Contributor), Mills, A. M. (Contributor), Lutz, M. (Contributor), Spek, A. L. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 1 Jan 2005
DOI: 10.5517/cc8lhlx, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8lhlx&sid=DataCite
Dataset / Software: Dataset

Cite this

@article{7b213e90f49d4a139db720c80155a069,

title = "Strained Stable 2-Aza-1-Phosphabicyclo[/n/.1.0]alkane and -alkene Fe(CO4) Complexes with Dynamic Phosphinidene Behavior",

abstract = "The synthesis of highly strained bicyclic phosphirane and phosphirene iron-tetracarbonyl complexes, that is, complexes with 2-aza-l-phosphabicyclo[n. 1.0]alkanes and -alkenes (n = 3-5), is explored by using intramolecular cycloaddition of an in situ generated electrophilic phosphinidene complex, [R(iPr)NP=Fe(CO)",

author = "M.L.G. Borst and {van der Riet}, N. and R.H. Lemmens and {De Kanter}, F.J.J. and M. Schakel and A.W. Ehlers and A.M. Mills and M. Lutz and A.L. Spek and K. Lammertsma",

year = "2005",

doi = "10.1002/chem.200401249",

language = "English",

volume = "11",

pages = "3631--3642",

journal = "Chemistry: A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

}

TY - JOUR

T1 - Strained Stable 2-Aza-1-Phosphabicyclo[/n/.1.0]alkane and -alkene Fe(CO4) Complexes with Dynamic Phosphinidene Behavior

AU - Borst, M.L.G.

AU - van der Riet, N.

AU - Lemmens, R.H.

AU - De Kanter, F.J.J.

AU - Schakel, M.

AU - Ehlers, A.W.

AU - Mills, A.M.

AU - Lutz, M.

AU - Spek, A.L.

AU - Lammertsma, K.

PY - 2005

Y1 - 2005

N2 - The synthesis of highly strained bicyclic phosphirane and phosphirene iron-tetracarbonyl complexes, that is, complexes with 2-aza-l-phosphabicyclo[n. 1.0]alkanes and -alkenes (n = 3-5), is explored by using intramolecular cycloaddition of an in situ generated electrophilic phosphinidene complex, [R(iPr)NP=Fe(CO)

AB - The synthesis of highly strained bicyclic phosphirane and phosphirene iron-tetracarbonyl complexes, that is, complexes with 2-aza-l-phosphabicyclo[n. 1.0]alkanes and -alkenes (n = 3-5), is explored by using intramolecular cycloaddition of an in situ generated electrophilic phosphinidene complex, [R(iPr)NP=Fe(CO)

U2 - 10.1002/chem.200401249

DO - 10.1002/chem.200401249

M3 - Article

SN - 0947-6539

VL - 11

SP - 3631

EP - 3642

JO - Chemistry: A European Journal

JF - Chemistry: A European Journal

ER -

Strained Stable 2-Aza-1-Phosphabicyclo[/n/.1.0]alkane and -alkene Fe(CO4) Complexes with Dynamic Phosphinidene Behavior

Abstract

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Datasets

CCDC 256108: Experimental Crystal Structure Determination

CCDC 256107: Experimental Crystal Structure Determination

CCDC 256109: Experimental Crystal Structure Determination

Cite this