The circumambulation of a Phosphirane: Taking 9-phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene for a "Walk"

R.E. Bulo; H.-. Jansen; A.W. Ehlers; F.J.J. De Kanter; M. Schakel; M. Lutz; A.L Spek; K. Lammertsma

doi:10.1002/anie.200351855

The circumambulation of a Phosphirane: Taking 9-phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene for a "Walk"

R.E. Bulo, H.-. Jansen, A.W. Ehlers, F.J.J. De Kanter, M. Schakel, M. Lutz, A.L Spek, K. Lammertsma

Organic Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Walking rings: At room temperature, the P-R entity of a bicyclic phosphirane (see picture) "walks" along the perimeter of the larger ring. Although this concerted rearrangement is similar to that of its hydrocarbon analogue, the additional 1,5-sigmatropic shift follows a different mechanism.

Original language	English
Pages (from-to)	714-717
Journal	Angewandte Chemie International Edition in English
Volume	43
DOIs	https://doi.org/10.1002/anie.200351855
Publication status	Published - 2004

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title = "The circumambulation of a Phosphirane: Taking 9-phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene for a {"}Walk{"}",

abstract = "Walking rings: At room temperature, the P-R entity of a bicyclic phosphirane (see picture) {"}walks{"} along the perimeter of the larger ring. Although this concerted rearrangement is similar to that of its hydrocarbon analogue, the additional 1,5-sigmatropic shift follows a different mechanism.",

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doi = "10.1002/anie.200351855",

language = "English",

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AU - Bulo, R.E.

AU - Jansen, H.-.

AU - Ehlers, A.W.

AU - De Kanter, F.J.J.

AU - Schakel, M.

AU - Lutz, M.

AU - Spek, A.L

AU - Lammertsma, K.

PY - 2004

Y1 - 2004

N2 - Walking rings: At room temperature, the P-R entity of a bicyclic phosphirane (see picture) "walks" along the perimeter of the larger ring. Although this concerted rearrangement is similar to that of its hydrocarbon analogue, the additional 1,5-sigmatropic shift follows a different mechanism.

AB - Walking rings: At room temperature, the P-R entity of a bicyclic phosphirane (see picture) "walks" along the perimeter of the larger ring. Although this concerted rearrangement is similar to that of its hydrocarbon analogue, the additional 1,5-sigmatropic shift follows a different mechanism.

U2 - 10.1002/anie.200351855

DO - 10.1002/anie.200351855

M3 - Article

SN - 0570-0833

VL - 43

SP - 714

EP - 717

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

ER -

The circumambulation of a Phosphirane: Taking 9-phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene for a "Walk"

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