The Donor-Stabilized Silylene Bis[N,N´-diisopropylbenzamidinato(–)]silicon(ii): Synthesis, Electronic Structure, and Reactivity

K. Junold; M. Nutz; J.A. Baus; C. Burschka; C. Fonseca Guerra; F.M. Bickelhaupt; R. Tacke

doi:10.1002/chem.201402483

The Donor-Stabilized Silylene Bis[N,N´-diisopropylbenzamidinato(–)]silicon(ii): Synthesis, Electronic Structure, and Reactivity

K. Junold, M. Nutz, J.A. Baus, C. Burschka, C. Fonseca Guerra, F.M. Bickelhaupt, R. Tacke

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

A convenient and robust synthesis of bis[N,N′- diisopropylbenzamidinato(-)]silicon(II) (1), a donor-stabilized silylene, has been developed (35 g scale). To get further information about the reactivity profile of 1, a series of oxidative addition reactions were studied. Treatment of 1 with PhSe-SePh (Se-Se bond activation), C

Original language	English
Pages (from-to)	9319-9329
Journal	Chemistry: A European Journal
Issue number	20
DOIs	https://doi.org/10.1002/chem.201402483
Publication status	Published - 2014

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10.1002/chem.201402483

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CCDC 983211: Experimental Crystal Structure Determination
Junold, K. (Contributor), Nutz, M. (Contributor), Baus, J. A. (Contributor), Burschka, C. (Contributor), Guerra, C. F. (Contributor), Bickelhaupt, M. (Contributor) & Tacke, R. (Contributor), Unknown Publisher, 21 Jul 2014
DOI: 10.5517/cc1203hp, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1203hp&sid=DataCite
Dataset / Software: Dataset
CCDC 983214: Experimental Crystal Structure Determination
Junold, K. (Contributor), Nutz, M. (Contributor), Baus, J. A. (Contributor), Burschka, C. (Contributor), Guerra, C. F. (Contributor), Bickelhaupt, M. (Contributor) & Tacke, R. (Contributor), Unknown Publisher, 21 Jul 2014
DOI: 10.5517/cc1203ls, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1203ls&sid=DataCite
Dataset / Software: Dataset
CCDC 983213: Experimental Crystal Structure Determination
Junold, K. (Contributor), Nutz, M. (Contributor), Baus, J. A. (Contributor), Burschka, C. (Contributor), Guerra, C. F. (Contributor), Bickelhaupt, M. (Contributor) & Tacke, R. (Contributor), Unknown Publisher, 21 Jul 2014
DOI: 10.5517/cc1203kr, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1203kr&sid=DataCite
Dataset / Software: Dataset

Cite this

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title = "The Donor-Stabilized Silylene Bis[N,N´-diisopropylbenzamidinato(–)]silicon(ii): Synthesis, Electronic Structure, and Reactivity",

abstract = "A convenient and robust synthesis of bis[N,N′- diisopropylbenzamidinato(-)]silicon(II) (1), a donor-stabilized silylene, has been developed (35 g scale). To get further information about the reactivity profile of 1, a series of oxidative addition reactions were studied. Treatment of 1 with PhSe-SePh (Se-Se bond activation), C",

author = "K. Junold and M. Nutz and J.A. Baus and C. Burschka and {Fonseca Guerra}, C. and F.M. Bickelhaupt and R. Tacke",

year = "2014",

doi = "10.1002/chem.201402483",

language = "English",

pages = "9319--9329",

journal = "Chemistry: A European Journal",

issn = "0947-6539",

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T1 - The Donor-Stabilized Silylene Bis[N,N´-diisopropylbenzamidinato(–)]silicon(ii): Synthesis, Electronic Structure, and Reactivity

AU - Junold, K.

AU - Nutz, M.

AU - Baus, J.A.

AU - Burschka, C.

AU - Fonseca Guerra, C.

AU - Bickelhaupt, F.M.

AU - Tacke, R.

PY - 2014

Y1 - 2014

N2 - A convenient and robust synthesis of bis[N,N′- diisopropylbenzamidinato(-)]silicon(II) (1), a donor-stabilized silylene, has been developed (35 g scale). To get further information about the reactivity profile of 1, a series of oxidative addition reactions were studied. Treatment of 1 with PhSe-SePh (Se-Se bond activation), C

AB - A convenient and robust synthesis of bis[N,N′- diisopropylbenzamidinato(-)]silicon(II) (1), a donor-stabilized silylene, has been developed (35 g scale). To get further information about the reactivity profile of 1, a series of oxidative addition reactions were studied. Treatment of 1 with PhSe-SePh (Se-Se bond activation), C

U2 - 10.1002/chem.201402483

DO - 10.1002/chem.201402483

M3 - Article

SN - 0947-6539

SP - 9319

EP - 9329

JO - Chemistry: A European Journal

JF - Chemistry: A European Journal

IS - 20

ER -

The Donor-Stabilized Silylene Bis[N,N´-diisopropylbenzamidinato(–)]silicon(ii): Synthesis, Electronic Structure, and Reactivity

Abstract

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Datasets

CCDC 983211: Experimental Crystal Structure Determination

CCDC 983214: Experimental Crystal Structure Determination

CCDC 983213: Experimental Crystal Structure Determination

Cite this