Thermodynamic and kinetic aspects of the electron transfer reaction of bovine cytochrome c immobilized on 4-mercaptopyridine and 11-mercapto-1-undecanoic acid films

S. Monari; G. Battistuzzi; M. Borsari; D. Millo; C. Gooijer; G. der Van Zwan; A. Ranieri; M. Sola

doi:10.1007/s10800-008-9493-7

Thermodynamic and kinetic aspects of the electron transfer reaction of bovine cytochrome c immobilized on 4-mercaptopyridine and 11-mercapto-1-undecanoic acid films

S. Monari, G. Battistuzzi, M. Borsari, D. Millo, C. Gooijer, G. der Van Zwan, A. Ranieri, M. Sola

BioAnalytical Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Bovine cytochrome c (cyt c) was adsorbed on a polycrystalline gold electrode coated with 4-mercaptopyridine and 11-mercapto-1-undecanoic acid self-assembled monolayers (SAMs) and the thermodynamics and kinetics of the heterogeneous protein-electrode electron transfer (ET) reaction were determined by cyclic voltammetry. The E°′ values for the immobilized protein were found to be lower than those for the corresponding diffusing species. The thermodynamic parameters for protein reduction (δH°′

Original language	English
Pages (from-to)	885-891
Journal	Journal of Applied Electrochemistry
Volume	38
Issue number	7
DOIs	https://doi.org/10.1007/s10800-008-9493-7
Publication status	Published - 2008

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10.1007/s10800-008-9493-7

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Monari, S., Battistuzzi, G., Borsari, M., Millo, D., Gooijer, C., der Van Zwan, G., Ranieri, A., & Sola, M. (2008). Thermodynamic and kinetic aspects of the electron transfer reaction of bovine cytochrome c immobilized on 4-mercaptopyridine and 11-mercapto-1-undecanoic acid films. Journal of Applied Electrochemistry, 38(7), 885-891. https://doi.org/10.1007/s10800-008-9493-7

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title = "Thermodynamic and kinetic aspects of the electron transfer reaction of bovine cytochrome c immobilized on 4-mercaptopyridine and 11-mercapto-1-undecanoic acid films",

abstract = "Bovine cytochrome c (cyt c) was adsorbed on a polycrystalline gold electrode coated with 4-mercaptopyridine and 11-mercapto-1-undecanoic acid self-assembled monolayers (SAMs) and the thermodynamics and kinetics of the heterogeneous protein-electrode electron transfer (ET) reaction were determined by cyclic voltammetry. The E°′ values for the immobilized protein were found to be lower than those for the corresponding diffusing species. The thermodynamic parameters for protein reduction (δH°′",

author = "S. Monari and G. Battistuzzi and M. Borsari and D. Millo and C. Gooijer and {der Van Zwan}, G. and A. Ranieri and M. Sola",

year = "2008",

doi = "10.1007/s10800-008-9493-7",

language = "English",

volume = "38",

pages = "885--891",

journal = "Journal of Applied Electrochemistry",

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Monari, S, Battistuzzi, G, Borsari, M, Millo, D, Gooijer, C, der Van Zwan, G, Ranieri, A & Sola, M 2008, 'Thermodynamic and kinetic aspects of the electron transfer reaction of bovine cytochrome c immobilized on 4-mercaptopyridine and 11-mercapto-1-undecanoic acid films', Journal of Applied Electrochemistry, vol. 38, no. 7, pp. 885-891. https://doi.org/10.1007/s10800-008-9493-7

Thermodynamic and kinetic aspects of the electron transfer reaction of bovine cytochrome c immobilized on 4-mercaptopyridine and 11-mercapto-1-undecanoic acid films. / Monari, S.; Battistuzzi, G.; Borsari, M. et al.
In: Journal of Applied Electrochemistry, Vol. 38, No. 7, 2008, p. 885-891.

Research output: Contribution to Journal › Article › Academic › peer-review

TY - JOUR

T1 - Thermodynamic and kinetic aspects of the electron transfer reaction of bovine cytochrome c immobilized on 4-mercaptopyridine and 11-mercapto-1-undecanoic acid films

AU - Monari, S.

AU - Battistuzzi, G.

AU - Borsari, M.

AU - Millo, D.

AU - Gooijer, C.

AU - der Van Zwan, G.

AU - Ranieri, A.

AU - Sola, M.

PY - 2008

Y1 - 2008

N2 - Bovine cytochrome c (cyt c) was adsorbed on a polycrystalline gold electrode coated with 4-mercaptopyridine and 11-mercapto-1-undecanoic acid self-assembled monolayers (SAMs) and the thermodynamics and kinetics of the heterogeneous protein-electrode electron transfer (ET) reaction were determined by cyclic voltammetry. The E°′ values for the immobilized protein were found to be lower than those for the corresponding diffusing species. The thermodynamic parameters for protein reduction (δH°′

AB - Bovine cytochrome c (cyt c) was adsorbed on a polycrystalline gold electrode coated with 4-mercaptopyridine and 11-mercapto-1-undecanoic acid self-assembled monolayers (SAMs) and the thermodynamics and kinetics of the heterogeneous protein-electrode electron transfer (ET) reaction were determined by cyclic voltammetry. The E°′ values for the immobilized protein were found to be lower than those for the corresponding diffusing species. The thermodynamic parameters for protein reduction (δH°′

U2 - 10.1007/s10800-008-9493-7

DO - 10.1007/s10800-008-9493-7

M3 - Article

SN - 0021-891X

VL - 38

SP - 885

EP - 891

JO - Journal of Applied Electrochemistry

JF - Journal of Applied Electrochemistry

IS - 7

ER -

Thermodynamic and kinetic aspects of the electron transfer reaction of bovine cytochrome c immobilized on 4-mercaptopyridine and 11-mercapto-1-undecanoic acid films

Abstract

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