Unexpected trends in halogen-bond based noncovalent adducts

Stefan M Huber; Elisa Jimenez-Izal; Jesus M. Ugalde; Ivan Infante

doi:10.1039/c2cc33304j

Unexpected trends in halogen-bond based noncovalent adducts

Stefan M Huber, Elisa Jimenez-Izal, Jesus M. Ugalde, Ivan Infante

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Unexpected trends in the strengths of halogen-bond based adducts of CY3I (Y = F, Cl, Br, I) with two typical Lewis bases (chloride and trimethylamine) show that the halogen-bond donor strength (Lewis acidity) of a compound R–X is not necessarily increased with higher electronegativity of the (carbon-based) group R.

Original language	English
Pages (from-to)	7708-7710
Number of pages	3
Journal	Chemical Commununications
DOIs	https://doi.org/10.1039/c2cc33304j
Publication status	Published - 2012

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title = "Unexpected trends in halogen-bond based noncovalent adducts",

abstract = "Unexpected trends in the strengths of halogen-bond based adducts of CY3I (Y = F, Cl, Br, I) with two typical Lewis bases (chloride and trimethylamine) show that the halogen-bond donor strength (Lewis acidity) of a compound R–X is not necessarily increased with higher electronegativity of the (carbon-based) group R.",

author = "Huber, {Stefan M} and Elisa Jimenez-Izal and Ugalde, {Jesus M.} and Ivan Infante",

year = "2012",

doi = "10.1039/c2cc33304j",

language = "English",

pages = "7708--7710",

journal = "Chemical Commununications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Unexpected trends in halogen-bond based noncovalent adducts

AU - Huber, Stefan M

AU - Jimenez-Izal, Elisa

AU - Ugalde, Jesus M.

AU - Infante, Ivan

PY - 2012

Y1 - 2012

N2 - Unexpected trends in the strengths of halogen-bond based adducts of CY3I (Y = F, Cl, Br, I) with two typical Lewis bases (chloride and trimethylamine) show that the halogen-bond donor strength (Lewis acidity) of a compound R–X is not necessarily increased with higher electronegativity of the (carbon-based) group R.

AB - Unexpected trends in the strengths of halogen-bond based adducts of CY3I (Y = F, Cl, Br, I) with two typical Lewis bases (chloride and trimethylamine) show that the halogen-bond donor strength (Lewis acidity) of a compound R–X is not necessarily increased with higher electronegativity of the (carbon-based) group R.

U2 - 10.1039/c2cc33304j

DO - 10.1039/c2cc33304j

M3 - Article

C2 - 22745936

SN - 1359-7345

SP - 7708

EP - 7710

JO - Chemical Commununications

JF - Chemical Commununications

ER -

Unexpected trends in halogen-bond based noncovalent adducts

Abstract

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