Valence isomerization of cyclohepta-1,3,5-triene and its heteroelement analogues

H. Jansen, J.C. Slootweg, K. Lammertsma

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Abstract

The valence isomerization of the all-carbon and heteroelement analogues of cyclohepta-1,3,5-triene into the corresponding bicyclo[4.1.0]hepta-2,4-dienes is reviewed to show the impact of the heteroatom on the stability of both valence isomers. The focus is on the parent systems and their synthetic applications. © 2011 Jansen et al; licensee Beilstein-Institut.
Original languageEnglish
Pages (from-to)1713-1721
JournalBeilstein Journal of Organic Chemistry
Volume7
DOIs
Publication statusPublished - 2011

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