Valence Isomerization of Phosphepines

H. Jansen, J.C. Slootweg, A.W. Ehlers, K. Lammertsma

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents. © 2010 American Chemical Society.
Original languageEnglish
Pages (from-to)6653-6659
JournalOrganometallics
Issue number29
DOIs
Publication statusPublished - 2010

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