Valence Isomerization of Phosphepines

H. Jansen; J.C. Slootweg; A.W. Ehlers; K. Lammertsma

doi:10.1021/om1004379

Valence Isomerization of Phosphepines

H. Jansen
, J.C. Slootweg
, A.W. Ehlers
, K. Lammertsma

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Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents. © 2010 American Chemical Society.

Original language	English
Pages (from-to)	6653-6659
Journal	Organometallics
Issue number	29
DOIs	https://doi.org/10.1021/om1004379
Publication status	Published - 2010

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title = "Valence Isomerization of Phosphepines",

abstract = "Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents. {\textcopyright} 2010 American Chemical Society.",

author = "H. Jansen and J.C. Slootweg and A.W. Ehlers and K. Lammertsma",

year = "2010",

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T1 - Valence Isomerization of Phosphepines

AU - Jansen, H.

AU - Slootweg, J.C.

AU - Ehlers, A.W.

AU - Lammertsma, K.

PY - 2010

Y1 - 2010

N2 - Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents. © 2010 American Chemical Society.

AB - Valence isomerization of phosphepines into phosphanorcaradienes has been studied computationally to facilitate the development of novel, metal-free phosphinidene precursors that controllably release singlet phosphinidenes upon heating. This target becomes viable by benzannulation of the seven-membered phosphepine ring and the introduction of P-amino substituents. © 2010 American Chemical Society.

U2 - 10.1021/om1004379

DO - 10.1021/om1004379

M3 - Article

SN - 1520-6041

SP - 6653

EP - 6659

JO - Organometallics

JF - Organometallics

IS - 29

ER -

Valence Isomerization of Phosphepines

Abstract

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